Tintin and the Golden Fleece (1961)
Tintin and the Golden Fleece (in the original French, Tintin et le mystère de la Toison d'or, meaning Tintin and the Mystery of the Golden Fleece) is a film first released in France on 6 December 1961. Featuring characters from the The Adventures of Tintin comic book series written and drawn by the Belgian writer-artist Hergé, it was a live-action film with actors made-up to look like the characters and featured an original storyline not based on any of the books.
More at Wikipedia.